I was eagerly looking forward to this collection for months! The episodes chosen are all excellent episodes and, for the most part, exemplify the Captain in question (though Patrick Stewart admits on his introduction that he chose "In Theory", a Data episode, because it was his directorial debut).
With Deep Space Nine being my personal favorite of the series, which has often been only minimally-represented by previous Fan Collectives, it was gratifying to see three of my favorite episodes from this excellent series chosen, including the 2-for-1 series finale.
My only complaint, as with the previous four Fan Collectives, was the limited number of episodes. Granted the Q set was as complete as it could be (save for the vague possible connection with "The Squire of Gothos") and there were only a few later Voyager Borg-episodes that might have fit with the Borg set. Still, the Klingon and Time Travel sets could easily have been twice as large (and I would have been willing to pay twice as much if they were) and so could the Captain's Log set.
Still, this set not only features great episodes but finally has some featurettes in addition to them, though I did miss the witty and enjoyable text commentaries of the prior sets.
If you're a Star Trek fan strapped for cash, or a newcomer looking for a relatively inexpensive way to get to know these fine series, I would highly recommend the Star Trek Fan Collective: Captain's Log.
If any higher-ups in charge of such things somehow wanders here, by all means keep these sets coming! We still need Volumes 2 of the Klingon and Time Travel sets, the Vulcan set, the Romulan set, the Ferengi set, the Prime Directive set, the Mirror Universe set...