This book must have been as much fun for Kevin Kelly to write as it is to read. It's a little long but very easy to understand. It'll make you think and you are sure to enjoy thinking about the ideas and examples in here.
A more correct title might be "Out of Centralized Control." Kelly's point is that Nature is not a command and control monolith, but instead, a network of relatives, friends, neighbors, and sometimes predators. Nature does not control the Universe so much as it encourages cooperation within the Universe. The examples Kelly gives in the first few pages set the tone of the rest of the book. One is the flock of geese, which somehow knows its migration path from hemisphere to hemisphere even though none of the geese in the flock have ever flown it before.
As Kelly shows us, there are plenty of surprises in Nature. Uncertainty is built in. That's life ! Some readers might find it hard to believe that Nature is not particularly concerned about efficiency. It doesn't mind duplication, redundancy, and a little waste. It fact, it wants these things because they lead us to flexibility. Kelly's point in all this seems to be that Nature does not play by the numbers.
It might be even harder for some readers to believe, at first, that Nature creates new things out of nothing every day. But, Kelly will win you over on that point and many more. His "Nine Laws of God" which sum up the book in the last chapter made me want to read it a second time.
One nice companion to this book would be "Morphic Resonance and the The Presence of the Past: The Habits of Nature" by Ruppert Sheldrake. That book presents a theory that is considered radical by many, yet the critics usually concede that it's well reasoned and fills many of the gaps in our knowledge of Nature.
If you'd like to think about the theological implications of Kelly's ideas, try a few books about process theology, particularly these: "A Basic Introduction to Process Theology" by Robert Mesle, "What is Process Theology?" by Robert Mellert, and "Ominipotence and Other Theological Mistakes" by Charles Hartshorne.